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Sunday, 2 September 2012

NO METAL IN C-H BOND FORMATION

ChemCatChem 20113, No. 05, 827-829

Recently, several research groups have reported that the C-H bond arylation of aromatic compounds with haloarenes can be promoted by potassium or sodium tert-butoxide, without the addition of any exogenous transition metal species. 

These serendipitous discoveries are highlighted and summarized.

Shuichi Yanagisawa, Kenichiro Itami
tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes

tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes


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