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Wednesday, 7 March 2012

WATER OXIDATIONS

WATER OXIDATIONS



Simple and Efficient Iridium(III)-Catalyzed Water Oxidations
The complex made simple: Simple and commercially available iridium precursors are tested for their ability to promote water oxidation. The activity values of these precursors towards cerium(IV)-driven oxygen generation from water are comparable with values reported for more complicated iridium-based systems. A turnover frequency of 1700 h−1 is achieved with IrCl3

  1. Dr. Nicolas Marquet, 
  2. Felix Gärtner, 
  3. Dr. Sebastian Losse, 
  4. Marga-Martina Pohl, 
  5. Dr. Henrik Junge, 
  6. Prof. Dr. Matthias Beller*
    7. Article first published online: 26 JUL 2011,DOI: 10.1002/cssc.201100217












SIMPLE CATALYS IS USED TO CARRY OU THE OXIDATIONS IN WATER

ChemSusChem

Volume 4, Issue 11, pages 1598–1600, November 18, 2011

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