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Thursday, 3 July 2014

Selective fluorination of alkyl C–H bonds via photocatalysis

Graphical abstract: Selective fluorination of alkyl C–H bonds via photocatalysis

We report the generation of cationic N-radicals from Selectfluor® via energy transfer with anthraquinone as a photocatalyst for the fluorination of unactivated C–H bonds.

http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC01848F?utm_medium=email&utm_campaign=pub-CC-vol-50-issue-60&utm_source=toc-alert#!divAbstract


Selective fluorination of alkyl C–H bonds via photocatalysis

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*Corresponding authors
aSchool of Physical & Mathematical Sciences, Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
E-mail: choonhong@ntu.edu.sg
bDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
Chem. Commun., 2014,50, 8211-8214

DOI: 10.1039/C4CC01848F
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1 comment:

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