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Sunday 10 August 2014

Catalyst-free sulfonylation of activated alkenes for highly efficient synthesis of mono-substituted ethyl sulfones in water




Catalyst-free sulfonylation of activated alkenes for highly efficient synthesis of mono-substituted ethyl sulfones in water

Green Chem., 2014, Advance Article
DOI: 10.1039/C4GC00932K, Communication
Yu Yang,a   Lin Tang,a   Sheng Zhang,a   Xuefeng Guo,a  Zhenggen Zhaa and   Zhiyong Wang*a   
 
*
Corresponding authors
a
Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry & Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, P. R. China
E-mail: zwang3@ustc.edu.cn;
Fax: (+86) 551-360-3185
Green Chem., 2014, Advance Article

DOI: 10.1039/C4GC00932K
A catalyst-free sulfonylation of activated alkenes developed under mild conditions in water.
 
 
 
 
  
A catalyst-free sulfonylation reaction of activated alkenes with sulfonyl hydrazides was efficiently developed under mild and environmentally benign conditions, in water without any ligand or additive. The reaction gave a range of structurally diverse mono-substituted ethyl sulfones with excellent yields, in which the by-product was nitrogen.

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