Kharasch-Sosnovsky Reaction:

Kharasch-Sosnovsky Reaction:

copper catalysed allylic oxidation using an organic peroxide.

reported by M. S. Kharasch and George Sosnovsky in 1958 ((DOI) DOI).

In the original publication the reactants are cyclohexene

and t-butyl perbenzoate with cuprous bromide and the

reaction product is cyclohex-1-en-3-yl benzoate:

 

Mechanism: (review: DOI). The reaction mechanism devised

by Beckwith et al (DOI) contains the following steps:

 

THANKS AND REGARD'S

DR ANTHONY MELVIN CRASTO Ph.D

amcrasto@gmail.com

MOBILE-+91 9323115463

GLENMARK SCIENTIST , NAVIMUMBAI, INDIA

web link

http://amcrasto.bravehost.com/

http://anthonycrasto.jimdo.com/

http://www.anthonymelvincrasto.yolasite.com/ 

http://www.slidestaxx.com/anthony-melvin-crasto-phd 

https://sites.google.com/site/anthonycrastoorganicchemistry/sites---my-own-on-the-net

http://amcrasto.biz.ly/

http://anthonycrasto.wordpress.com/