DR ANTHONY MELVIN CRASTO,WorldDrugTracker, helping millions, A 90 % paralysed man in action for you, I am suffering from transverse mylitis and bound to a wheel chair, With death on the horizon, nothing will not stop me except God
DR ANTHONY MELVIN CRASTO Ph.D ( ICT, Mumbai) , INDIA 30 Yrs Exp. in the feld of Organic Chemistry. Serving chemists around the world. Helping them with websites on Chemistry.Millions of hits on google, world acclamation from industry, academia, drug authorities for websites, blogs and educational contribution
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Wednesday 16 July 2014

Anthony crasto’s blog New drug approvals touches 3 lakh views…….Helping millions


All about Drugs, live, by DR ANTHONY MELVIN CRASTO, Worlddrugtracker, Helping millions, 7 million hits on google, pushing boundaries, one lakh plus connections worldwide, 3 lakh plus VIEWS on this blog in 193 countries




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Tuesday 15 July 2014

Convenient Synthesis of Benzothiazoles and Benzimidazoles through Brønsted Acid Catalyzed Cyclization of 2-Amino Thiophenols/Anilines with β-Diketones

Figure
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 http://pubs.acs.org/doi/abs/10.1021/ol403475v
pp 764–767
Publication Date (Web): January 10, 2014 (Letter)
DOI: 10.1021/ol403475v
 
 
 Brønsted acid catalyzed cyclization reactions of 2-amino thiophenols/anilines with β-diketones under oxidant-, metal-, and radiation-free conditions are described. Various 2-substituted benzothiazoles/benzimidazoles are obtained in satisfactory to excellent yields. Different groups such as methyl, chloro, nitro, and methoxy linked on benzene rings were tolerated under the optimized reaction conditions.

Thursday 10 July 2014

Cascade Reaction to 1,5-Disubstituted Imidazoles



 thumbnail image: Cascade Reaction to 1,5-Disubstituted Imidazoles

 

 

Cascade Reaction to 1,5-Disubstituted Imidazoles

Aerobic photocatalytic oxidation, [3+2] cycloaddition, and aromatization lead to desired products
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http://www.chemistryviews.org/details/ezine/6350031/Cascade_Reaction_to_15-Disubstituted_Imidazoles.html

Enantioselective Synthesis of Tetrahydrofuran Derivatives



 thumbnail image: Enantioselective Synthesis of Tetrahydrofuran Derivatives

 

Enantioselective Synthesis of Tetrahydrofuran Derivatives

Sequential one-pot Cu-catalyzed asymmetric Henry reaction and iodocyclization of γ,δ-unsaturated alcohols
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 http://www.chemistryviews.org/details/ezine/6333621/Enantioselective_Synthesis_of_Tetrahydrofuran_Derivatives.html

Functionalized γ-Resorcylates



 thumbnail image: Functionalized γ-Resorcylates


Functionalized γ-Resorcylates

Efficient route to functionalized γ-resorcylate compounds from dioxinone derivatives
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http://www.chemistryviews.org/details/ezine/6330921/Functionalized_-Resorcylates.html

Cross-Diinsertion of C≡N/C≡C into an N–H Bond



 thumbnail image: Cross-Diinsertion of C≡N/C≡C into an N–H Bond

http://www.chemistryviews.org/details/news/6323131/Cross-Diinsertion_of_CNCC_into_an_NH_Bond.html

Cross-Diinsertion of C≡N/C≡C into an N–H Bond

Facile synthesis of 1,2,4-trisubstituted imidazoles from propargylamines and nitriles
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Taming Living Carbocations for Conjugate Addition



 

thumbnail image: Taming Living Carbocations for Conjugate Addition

Taming Living Carbocations for Conjugate Addition

Direct conjugate addition of alkenes to α,β-enones is described
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 http://www.chemistryviews.org/details/ezine/6274181/Taming_Living_Carbocations_for_Conjugate_Addition.html